Assembly of strongly phosphorescent hetero-bimetallic and -trimetallic [2]catenane structures based on a coinage metal alkynyl system
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چکیده
منابع مشابه
Assembly of strongly phosphorescent hetero-bimetallic and -trimetallic [2]catenane structures based on a coinage metal alkynyl system† †Electronic supplementary information (ESI) available: Experimental details. CCDC 1499658 (1), 1499630 (2), 1499654 (3), 1554172 (4), 1554173 (5), 1554171 (6), and 1554174 (7). For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c7sc03529b
Homo-metallic metal alkynyl complexes exhibit interesting catenane structures, but their hetero-metallic catenane counterparts are under-developed. In this work, we report rare examples of bimetallic Au–Cu (DtbpC^C ligand; Dtbp 1⁄4 3,5-di-tert-butylphenyl), Au–Ag (BuC^C ligand), and Au–Cu, Au–Ag (C6FluoC^C ligand; C6-Fluo 1⁄4 9,9-dihexyl-9H-fluoren-2-yl) complexes as well as a trimetallic Au–Ag...
متن کاملAlkynyl-functionalized gold NHC complexes and their coinage metal clusters.
Phenylpropynyl-functionalized imidazolium salts, as well as their gold complexes, were prepared in excellent yields affording suitable starting materials for metal cluster synthesis. The reactions of these gold complexes with coinage metal phenylacetylides [M(CCPh)](x) (M = Cu, Ag) resulted in the formation of novel heterometallic hexanuclear clusters which exhibit mixed metallophillic interact...
متن کاملCorrection: Alkynyl-functionalized gold NHC complexes and their coinage metal clusters.
The authors regret that the incorrect CCDC numbers have been quoted in the footnote referencing the Electronic Supplementary Information (ESI) on the first page of the above article. The correct ESI footnote is shown below with CCDC numbers 1059550–1059555 as quoted in the Acknowledgments, and not 1040816–1040823. The CIF files posted originally were also incorrect. These were replaced with the...
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ژورنال
عنوان ژورنال: Chem. Sci.
سال: 2017
ISSN: 2041-6520,2041-6539
DOI: 10.1039/c7sc03529b